1. The Summit-Five Affair
Air date: 1967-09-11 · 60 min
Just before the U.N.C.L.E. Summit-Five meeting when the regional leaders gather to activate new communication codes, an agent turns up dead... and Napoleon is seemingly the killer.
Open episode 1 ↗2. The Test Tube Killer Affair
Air date: 1967-09-18 · 60 min
Napoleon and Illya try to stop Thrush's "perfect assassin," who has been trained to shut off his emotions and do whatever is necessary to complete his mission.
Open episode 2 ↗3. The 'J' for Judas Affair
Air date: 1967-09-25 · 60 min
Thrush is working with someone within the Tenza industrial empire to assassinate father Mark Tenza and his son Adam.
Open episode 3 ↗4. The Prince of Darkness Affair: Part I
Air date: 1967-10-02 · 60 min
Illya and master safecracker Luther Sebastian infiltrate the laboratory of Dr. Kharmusi to steal a thermal prism, while Napoleon distracts the creator. However, the girlfriend of a man Lucius framed for murder is out for revenge.
Open episode 4 ↗5. The Prince of Darkness Affair: Part II
Air date: 1967-10-09 · 60 min
Luther gains the thermal prism and plans to hijack a U.S. rocket to launch it into orbit as a blackmail weapon.
Open episode 5 ↗6. The Master's Touch Affair
Air date: 1967-10-16 · 60 min
Pharos Mandor, a former Thrush director, plays Thrush off against U.N.C.L.E. by pretending to defect and provide U.N.C.L.E. with inside information... that discredits his rivals in Thrush.
Open episode 6 ↗7. The Thrush Roulette Affair
Air date: 1967-10-23 · 60 min
The owner of a Caribbean casino, secretly a Thrush operative, uses the casino to brainwash his organization's enemies... and Illya is the next target.
Open episode 7 ↗8. The Deadly Quest Affair
Air date: 1967-10-30 · 60 min
A former adversary, believed dead, abducts Illya and uses him as bait to lure Napoleon into a deadly game of cat & mouse in an abandoned block of buildings in New York City.
Open episode 8 ↗9. The Fiery Angel Affair
Air date: 1967-11-06 · 60 min
Napoleon and Illya must protect the charismatic female leader of a South American company from an organization work for Thrush that mean to see her out of office... one way or another.
Open episode 9 ↗10. The Survival School Affair
Air date: 1967-11-20 · 60 min
Illya goes on a solo mission to an isolated U.N.C.L.E. training school to find out who in attendance is a Thrush mole.
Open episode 10 ↗11. The Gurnius Affair
Air date: 1967-11-27 · 60 min
Napoleon and Illya go after a missing Nazi scientist, and discover that Thrush wants him because he can develop a mind-control ray\ for them.
Open episode 11 ↗12. The Man from Thrush Affair
Air date: 1967-12-04 · 60 min
With the help of a local U.N.C.L.E. agent, Napoleon infiltrates a Greek island that serves as a Thrush base of operations.
Open episode 12 ↗13. The Maze Affair
Air date: 1967-12-18 · 60 min
Thrush sets up an elaborate trap to obtain a molecutronic gun from a scientist, stealing it from under U.N.C.L.E.'s noses... or so U.N.C.L.E. think.
Open episode 13 ↗14. The Deep Six Affair
Air date: 1967-12-25 · 60 min
A British U.N.C.L.E. agent is getting married. However, a Thrush commander, Koehler, kidnaps the man's fiancee and forces him to steal the plans for a supersubmarine.
Open episode 14 ↗15. The Seven Wonders of the World Affair (1)
Air date: 1968-01-08 · 60 min
U.N.C.L.E. official Robert Kingsley disappears, intending to conquer the world for good by using a docility gas. He's unaware that Thrush is using his wife to betray him.
Open episode 15 ↗16. The Seven Wonders of the World Affair (2)
Air date: 1968-01-15 · 60 min
With time running out, Napoleon and Illya face a firing squad when they fail to convince the "Seven Wonders" to turn against Kingsley and Thrush.
Open episode 16 ↗